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Item 2 4014. Co DUETTM c a(n <e Dual- Action Adulticide For use only by federal, state, tribal or local government officials responsible for public health or vector material beyond the body of water in order to minimize incidental deposition into the water body. Do control, or by persons certified in the appropriate category or otherwise authorized by the state or tribal not contaminate bodies of water when disposing of equipment rinsate or wash waters. lead pesticide regulatory agency to perform adult mosquito control applications, or by persons under their direct supenvsion. This product is highly toxic to bees exposed to direct treatment on blooming crops or weeds. Do not A Quick Knockdown, Oil Soluble Synergized Synthetic Pyrethroid for Effective Control of Adult apply to or allow drift onto blooming crops or weeds when bees are visiting the treatment area, except determined when applications are made to prevent or control a threat to pubic and/or animal heal Mosquitoes, Gnats, Biting and Non - Biting Midges and Blackflies in Outdoor Residential & Recreational th rmined by Areas a state, tribal or local health or vector control agency on the basis of documented evidence of disease causing agents in vector mosquitoes, a the occurrence of mosquito-borne disease in animal or human ACTIVE INGREDIENTS populations, or if specifically approved by the state or trbe during a natural disaster recovery effort. Prallethrin: (RS) -2- methyl- 4- oxo- 3- (2- propynyl) cydopent- 2 -enyl- PHYSICAL OR CHEMICAL HAZARDS (1 RS) -cis, trans- chrysanthemate 1.00% Do not use or store near heat or open flame. Sumit rin ©: 3- Phenoxybenzyl -(1 RS, 3RS,1 RS, 3SR)- 2,2- dmethyl -3 -(2- DIRECTIONS FOR USE mefhylprop- l -enyl) cyclopropanecarboxyiate 5.00% k is a violation of Federal Law to use this product In a manner inconsistent with ks labeling. Piperonyl Butoxide* 5.00% OTHER INGREDIENTS ** 89.00% USE RESTRICTIONS I 100.00% For use only by federal, state, tribal, or local government officials responsible for pubic health a Contains 0.075 bs of PraNethrin /talon, 0.375 lbs of Sumilhrn /Gallon and 0.375 Ibs of Piperonyl +rector control, or by persons certified in the appropriate category or otherwise authorized by the state Butoxide (PBO) /Galion or tribal lead pesticide regulatory agency to perform adult mosquito control applications, or by persons under their direct supervision. *(butyl carhityl) (6- propylpiperonyl) ether and related compounds "Contains petroleum distillate IN CALIFORNIA: This product is to be applied by County Health Department, State Department of Health Services, Mosquito and Vector Control of Mosquito Abatement District person only. KEEP OUT OF REACH OF CHILDREN IN FLORIDA Do not apply by afraaft unless approved by the Florida s • : 't • Ag ulture and Consumer Services. CAUTION Do not treat a site with more than 0.0036 fibs • S and • • • • bur ' x r • r • PRECAUCION AL USUARIO: Si usted no lee ingles, no use este producto hasta que la bs praletmrin)per awe in a 24 • • - ... Do of a 0. o • ' or y'.: yl butoxi., • etiqueta haya sido explicado ampliamente 0.021b prcileth ' • per acre in - si in • y ::. More • : • prevent or control - i• re- to pubic an. • m • - th : - • a - : .1. • • • health or vector • FIRST AID trot ag: • i : basis of • "' • : o chi : = ' .: g agents in vector mosquitoes Have the product container Or label with you when calling a poison con rol dente the occur ce mosgki (• - • : in . • unan populations, a if specificaly ap- or doctor, or going for treatment. For information regardin. 1• . • t gencies • °veil by th: -fate • = • • : natu : • salter recovery effort. pesticide incidents, call 1 -888 -740 -8712. _ ' 0 E: When to • • . • •ic , with other insecticides containing PBO, do not exceed 2 lbs PBO per au :r year. IF SWALLOWED: immediately ••issh con '• • me I t. • . 1 not nr s • not contaminate food, feed or drinking water Do not contaminate pastureland, rangeland, crop- ••••ngunl --st •Id• so - by :• • -,•Icen`roradoc • r. ` Cl* no •live y l i• th r • 1 • • +t give an land, poultry ranges or potade water supplies with spray thrift In treatment of corrals, feed lots, swine mouth to • lots and zoos, cover any exposed drinking water, drinking water fountains and animal feed before application. • T • - ICI : . tains . of ill s - vomiting may cause aspiration Not for use in outdoor residential misting systems. Not for use in metered release systems. P DUET cannot be diluted in water. Dilute this product with light mineral of if dilution is preferred. —"" USE INFORMAfiON . - PRECAUTIONARY STATEMENTS DUET is approved for ppr application as a thermal aerosol and as an Ultra Low Volume (ULV) nonthemmal HAZARDS TO HUMANS AND DOMESTIC ANIMALS aerosol (cold fog) in mosquito adiiliddng programs involving outdoor residential and recreational CAUTION. Harniful if swallowed. Wash thoroughly with soap and water after handing and before eat- areas where adult mosquitoes are present in annoying numbers, and in vegetation surrounding parks, ing, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. woodlands, swamps, marshes, overgrown areas and golf courses. Personal Protective Ecuiwnent (PPE1: Mixers, loaders, applicators, and other handlers must wear For best results, apply when mosquitoes are most active and meteorological conditions are conducive the following: long- sleeve shirt, long pants, shoes and socks. See engineering controls for additional to keeping the spray cloud close to the ground. Application in calm air conditions is to be avoided. requirements. Apply only when wind speed is greater than or equal to 1 mph. All types of applications should be User Safety Requirements: Follow manufacturer's instructions for cleaning /maintaining PPE. If no conducted at temperatures above 50 °F. such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately SPRAY DROPLET SIZE DETERMINATION from other laundry. Discard clothing and other absorbent material that have been drenched or heavily Ground- based, wide area mosquko abatement application: Spray equipment must be aclusted so contaminated with the product's concentrate. Do not reuse them. that the volume median diameter (VMD) is between 8 and 30 microns (Dv 0.5 < 30 um) and that 90% USER SAFETY RECOMMENDATIONS: Users should wash hands before eating, drinking, of the spray is contained in droplets smaller than 50 microns (Dv 0.9 < 50 um). Directions from the chewing gum, using tobacco, or using the toilet. Users should remove clothing/PPE immediately if equipment manufacturer or vendor, pesticide registrant, or a test fall ty using a laser -based measure - pesticide gets inside. Then wash thoroughly and put on clean clothing. Users should remove PPE ment instrument must be used to adjust equipment to produce acceptable droplet size spectra. Ap- e mediately after handling this product As soon as possible, wash thoroughly and change into pication equipment must be tested at least annually to confirm that pressure at the nozzle and nozzle clean clothing. flow rate(s) are property calibrated. Engineerino Controls: Pilots must use an enclosed cockpit that meets the requirements listed in the Aerial Equipment, wide area mosquito abatement application: Spray equipment must be adjusted Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(6)[. Human flagging so that the volume medan diameter produced is less than 60 microns (Dv 0.5 < 60 um) and that 90% is prohibited. Flagging to support aerial applications is limited to use of the Global Positioning System of the spray is contained in dtoplets smaller than 115 microns (Dv 0.9 < 115 um). The effects of flight a mechanical fiaggers. speed and, for non-rotary atomizers, nozzle angle on the droplet size spectrum must be considered. RiPrIMENTAL. HAZARDS 4 Diections from the equipment manufacturer or vendor, pesticide registrant, or a test feebly using a wind tunnel and laser -based measurement instrument rust be used to adjust equipment to produce This j>osiaide is highly bit kgsikiallikiiiiiianisms. iidudng fish and aquatic invertebrates. Runoff acceptable droplet size spectra. Application equipment must be tested at least annually to confirm that from treated areas or deposition of spray droplets into a body of water may be hazardous to fish and pressure at the nozzle and nozzle flow rate(s) are property calibrated. aquatic invertebrates. Before making the first application in a season, it is advisable to consult with the state or tribal agency with primary responsbiity for pesticide regulation to detemine if other regulatory GROUND U.L.V. APPLICATION requirements exist. Do not apply over bodies of water (lakes, rivers, permanent streams, natural To control Mosquitoes and other fisted insects, apply DUET at a flow rate of 2.5 to 7.4 fluid ounces per ponds, canmercial fish ponds, swamps, marshes a estuaries), except when necessary to target minute at an average vehide speed of 10 mph using a swath width of 300 feet for acreage calculations areas where adult mosquitoes are present, and weather conditions will facilitate movement of applied (see chart below). Under normal residential conditions a flow rate of 4.6 fluid ounces per minute is rec- AL0258 onmended. If a dfferent vehicle speed is used, adjust rate accordingly. These rates are equivalent to 0.00024 to 0.00072 pounds of prallethrin and 0.0012 to 0.0036 pounds of sumithrin and STORAGE & DISPOSAL piperonyl butoxide per acre. Vary flow rate accorcing to vegetation density and mosquito population. Do not contaminate water, food or feed by storage and disposal. Use higher flow rate in heavy vegetation or when populations are high. DUET may also be diluted PESTICIDE STORAGE: Store in a cool, with a suitable solvent such as mineral of and applied by GROUND ULV equipment so long as 1.23 place. Keep container closed. fluid ounces per acre of DUET is not exceeded. Refer to the dilution tables on this label for flow rate PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site calculations for cluted end -use formulations of DUET. or at an approved waste disposal facility. Pounds a.i. /Acre DUET Application Rates in Ft.oz. /Minute at truck speeds of: CONTAINER DISPOSAL: Prallethrin Sumithrin/ 5 MPH 10 MPH 15 MPH 20 MPH [For 2.5 -gallon Jugs]: Nonrefiflable container. Do not reuse or refill this container. Triple rinse PBO Fl. oz/Acre container (or equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a nix tank and drain for 10 seconds after the flow begins to 0.00072 0.0036 1.23 3.7 7.4 11.2 14.9 drip. Fill the container 1/4 fui with mineral all and recap. Shake for 10 secondes. Pour rinsate into 0.00044 0.0022 0.75 2.3 4.6 6.8 9.1 application equipment or a rinse tank or store tinsate for later use or disposal. Dram for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Offer for recycling if available 0.00036 0.0018 0.61 1.9 3.7 5.6 7.4 or reconditioning if appropriate, or puncture and dispose of in a sanitary landfill, or by other proce- 0.00024 0.0012 0.41 1.2 2.5 3.7 5.0 dures approved by state and local authorities. DUET may also be applied with non - thermal, portable, motorized backpack equipment adjusted to [For refillable drums & totes]: Refillable container. Refill this container with pesticide only. Do deliver ULV particles of less than 100 microns VMD. Use 0.41 to 1.23 fl.oz. of the undiluted spray per not reuse this container for any other purpose. Cleaning before refilling is the responsibility of I acre (equal to 0.0012 to 0.0036 Ib sumithrin/acre) as a 50 ft swath while waking at a speed of 2 mph. the refilled To clean the container before final disposal, empty the remaining contents from this Dilute with a suitable mineral oil if dilution is preferred. Do not exceed 1.23 fl.oz. of the undiluted spray container into application equipment or mix tank. Fill the container about 10 percent full with water. or acre. Do NOT use portable backpack equipment for application in enclosed aces. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into D a b P P P sP nnsate collection system. Repeat this rinsing procedure two more times. Offer for recycling if avail- DUET may be applied through truck mounted thermal fogging equipment. Do not exceed the able or reconditioning if appropriate, or puncture and dispose of in a sanitary landfill, or by other maximum rates listed above. May be applied at speeds of 5 to 20 mph. To reduce al requirement and procedures approved by state and local authorities. sludge buildup in equipment use a 60- 100 - second viscosity mineral "fog" oil or other fuel -type oil. Use a clean, well - maintained and property calibrated fogger. Do not wet foliage since oil base formulations may be phytotoxic. For use with hand - carried foggers, use same rates of active ingredient per acre and a swath width of 50 ft with a walking speed of 2 mph. Fog downwind, with the wind at your back. Do NOT use hand -carried foggers for application in enclosed spaces. FOR MORE INFORMATION CALL 1-800-323-5727 AERIAL APPLICATION NOTICE: To the extent provided by law, seller makes no warranty, expressed or implied, concerning the use of this product other than as indicated on the label. Buyer assumes all risk of use/handling of this material DUET may be applied at rates of 0.41 to 1.23 fl.oz DUET per acre by fixed wing or rotary aircraft when use anclor handling is contrary to label instructions. equipped with suitable ULV application equipment. Appropriate spray systems include rotary atom- DUET"' is a trademark of Clarke Mosquito Control Products, Inc. izers, flat fan, high pressure, and high pressure impaction nozzles characterized and oriented to achieve the droplet characteristics specified in this label. SumithrinT" is a trademark of Sumitomo Company Ltd. DUET may also be diluted with a suitable solvent such as mineral oil and applied by aerial ULV equip- ment so long as 1.23 fl.oz. per acre of DUET is not exceeded. Refer to the dilution tables on this label for flow rate calculations for diluted end -use formulations of DUET. Do not apply by fixed wing aircraft at a height less than 100 feet above the ground or canopy, or by helicopter at a height less than 75 feet above the ground or canopy unless specifically approved by the state or tribe based on public health needs. DILUTION CALCULATIONS For a 4% Sumithrin product dilute 1 gallon DUET with 0.25 gallon dl. Finished spray contains 0.3 Ib Sumithrin & PBO and 0.06 Ib prallethrin per gallon. Pounds a. i. /Acre Fluid oz Application Rates in Fl.oz. /Minute Dosage Finished at truck speeds of: Description Sumithrin/ S p ra y P Prallethrin PBO Acre 5 MPH 10 MPH 15 MPH 20 MPH High Population 0.00072 0.0036 1.54 4.7 9.3 14.0 18.6 Recommended 0.00044 0.0022 0.94 2.8 5.7 8.5 11.4 0.00036 0.0018 0.77 2.3 4.7 7,0 9.3 Light Population 0.00024 0.0012 0.51 1.6 3.1 4.7 6.2 For a 2.5% Sumithrin product, dilute 1 gallon DUET with 1 gallon oil. Finished spray contains 0.1875 b Sumithrin & PBO and 0.038 Ib prallethrin per gallon. Pounds a.i. /Acre Fluid oz Application Rates in Fl.oz. /Minute Dosage Finished at truck speeds of: Description Sumithrin/ Spray Per Prallethrn PBO Acre 5 MPH 10 MPH 15 MPH 20 MPH High Population 0.00072 0.0036 2.46 7.4 14.9 22.3 29.8 Recommended 0.00044 0.0022 1.50 4.6 9.1 13.7 18.2 0.00036 0.0018 1.23 3.7 7.4 11.2 14.9 Light Population 0.00024 0.0012 0.82 2.5 5.0 7.4 9.9 MANUFACTURED FOR product dilute 1 gallon DUET with 1.5 gallons oil. Finished CLARKE MOSQUITO CONTROL PRODUCTS, INC. For a 2% Sumithrin pr g g spray contains 0.15 159 N. GARDEN AVENUE Sumithrin & PBO and 0.03 Ib pralethrn per gallon. ROSELLE, ILLINOIS 60172 Pounds a.i. /Acre Fluid oz Application Rates in Fl.oz. /Minute Dosage Finished at truck speeds of: EPA REG. NO.: 1021 -1795 -8329 EPA EST. NO.: 8329 -IL -01 Description Sumithrin/ Sp per AVAILABLE PACKAGING: 2.5 GAL, 30 GAL, 55 GAL, 275 GAL TOTE Prallethrin PBO Acre 5 MPH 10 MPH 15 MPH 20 MPH High Population 0.00072 0.0036 3.07 9.3 18.6 27.9 37.2 LOT NO.: Marked on Container Label Recommended 0.00044 0.0022 1.88 5.7 11.4 17.1 22.8 0.00036 0.0018 1.54 4.7 9.3 14.0 18.6 Light Population 0.00024 0.0012 1.02 3.1 6.2 9.3 12.4 AL0258 Page 1 of 3 Material Safety Data Sheet Date Last revised: 6 June 6, 2008 I. General Information Chemical Name and Synonyms j Trade Name & Synonyms None: mixture/blend DUET Dual- action Adulticide Chemical Family EPA Registration Number Synergized Synthetic Pyrethroid 1021- 1795 -8329 Proper DOT/ICAO/IATA Shipping Name DOT/ICAO/IATA Hazard Classitkation Insecticides, Insect or Animal Repellent, Liquid, N.O.S. Non- Hazardous (in non- bulkguantities) Registrant Registrant's Phone Number Clarke Mosquito Control Products, Inc. (630) 894 -2000 Address 24 HOUR EMERGENCY TELEPHONE NUMBERS 159 North Garden Avenue EMERGENCY PHONE: (888) 740 -8712 Roselle, Illinois 60172 CHEMTREC U.S. and CANADA (800) 424 -9300 CHEMTREC All Other Areas (703)527 -3887 II. Ingredients Principal Hazardous Components ; Wt.% _ CAS # EINECS# Prallethrin (ETOC') i 1.0 023031 -36 -9 245 -387 -9 d- Phenothrin (Sumithrin 5.0 i 026002 -80 -2 247 -404 -5 Piperonyl Butoxide 5.0 000051 -03 -6 j 200 -076 -7 Petroleum Distillates ; 15 -25 064742 -47 -8 265 -149 -8 i i Mineral Oil i 50-75 i 008042 -47 -5 i 232 -455 -8 COMMENTS: Ingredients not identified are proprietary or non- hazardous. Values are not product specifications. III. Physical Data Boiling Point (°F): Not Available Specific Gravity (1120 = 1): 0.860 at 20 °C (68 °F) Vapor Pressure (mm Hg.): Not Available Vapor Density (Air = I): Heavier than air Solubility in Water: Immiscible in water 1 pH: Not Applicable Appearance: Clear, yellow - colored liquid (Gardner Scale 1.0) Odor: Solvent odor Viscosity: 18 CPS at 22 °C (71.6 °F) Brookfield ! (VOC): < 1.000% IV. Fire & Explosion Hazard Data Flash Point (Test Method : > 93.3 °C (200 °F) TAG Closed Cup _ Flammable Class: This product is NOT classified as flammable or combustible by OSHA Extinguishing Media: Foam, carbon dioxide, or dry chemical Hazardous Combustion Products: This product is classified as Non - Combustible, however in the extreme temperatures that fires may produce, some of the constituents of this formula may decompose to give off such gases as carbon dioxide, carbon monoxide, and nitrogen oxides. Special Fire Fighting Procedures: Treat as an oil fire. Use a full -faced self - contained breathing apparatus along with full protective gear. Keep nearby containers and equipment cool with a water stream. Sensitive to Static Discharge: Yes, use proper bonding and/or grounding procedures V. Health Hazard Data EMERGENCY OVERVIEW: CAUTION. Harmful if swallowed. Contains petroleum distillates; vomiting may cause aspiration pneumonia. Take prudent precautions to avoid contact with skin, eyes, and clothing. Do not use or store near heat or open flame. POTENTIAL HEALTH EFFECTS & EMERGENCY FIRST AID Skin Contact: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes, mouth). May be harmful if absorbed through the skin. Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 -20 minutes. Call a poison control center or doctor for treatment advice. Eye: May cause temporary irritation, tearing, and blurred vision. Hold eye open and rinse slowly and gently with water for 15 -20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing the eye. Call a poison control center or doctor for treatment advice. Inhalation: Excessive inhalation of mists can cause nasal and respiratory irritation. Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to -mouth if possible. Call a poison control center or doctor for further treatment advice. Page 2 of 3 Material Safety Data Sheet DUET Dual- action Adulticide Date last revised: 6 June 6, 2008 Ingestion: Harmful if swallowed. Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe lung injury. If swallowed, immediately call a poison control center or doctor for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person. Chronic Effects: None known NOTES TO PHYSICIAN: Contains pyrethroids and petroleum distillates; vomiting may pose an aspiration pneumonia hazard. For skin effects, a highly efficient therapeutic agent for pyrethroid exposure is topical application of Tocopherol Acetate (Vitamin E). VI. Reactivity Data Stable: ! YES Incompatibility : Strong acidic or alkaline materials. Not compatible with strong oxidizers. Hazardous Polymerization: I NO Vii, Environmental Protection Procedures Spill Response: Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. For large spills, collect product into drums, storage tanks, etc. via drains, pumps, etc. Absorb with appropriate absorbent such as sand, or vermiculate. Clean spill area of residues and absorbent. Environmental Precautions: Water Spill: Contains pyrethroids which are toxic to fish and other aquatic invertebrates. Contaminated absorbent and wash water should be disposed of according to local, state/provincial and federal /national regulations. Storage: Store in a cool, dry place. Keep container closed. Do not contaminate water, food or feedstuffs by storage, handling, or by disposal. Disposal Considerations: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Triple rinse (or equivalent) empty containers and offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other approved State and Local procedures RCRA/EPA Waste Information: None of the ingredients in this product appear on the RCRA lists (40 CFR 261.24, 40 CFR 25133) or CERCLA Hazardous Substance list (40 CFR Part 302 Table 302.4). Electrostatic Accumulation Hazard: This product contains petroleum distillates for which there is potential for the accumulation of static electricity. Consideration should be given to bonding and grounding of equipment during loading, unloading, and transfer of this product. VIII. Special Protection Information Exposure Guidelines (TWA) 1 OSHA PEL ACGIH TLV Supplier OEL Prallethrn (ETOC 1 None None None d- Phenothrin (Sumithrie) , None None None Piperonyl Butoxide ? None None None Petroleum Distillates None 5 mg/m3 (skin) 100 ppm / 525 mg/m3 Hydrotreated Paraffinic Oil i 5 mg/m3 (mist) 5 mg/m3 (mist) None Eye and Face Protection: Take prudent precautions to avoid contact with eyes. Skin Protection: Take prudent precautions to avoid contact with skin and clothing. Respiratory Protection: Wearing a respirator is not normally required when handling this product. Use in well ventilated areas. Engineering Controls:lvlechanical ventilation should be used when handling this product in enclosed spaces. Local exhaust ventilation maybe necessary. Work/Hygienic Practices: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK AREA. Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking, or using the toilet. IX. Toxicological Information Acute Dermal LD50 > 2000 mg/kg (albino rabbit) [ Acute Oral LD50 > 5000 mg/kg (albino rat) Inhalation LCSO The acute inhalation LC50 of this material places it in EPA toxicity category IV. Eye Effects: Irritation clearing in 24 hours. Skin Effects: Slight irritation at 72 hours. Irritation index = 0.90 Sensitization: Negative; Not considered to be a dermal sensitizer. COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA, or ACGIH as being carcinogens. Page 3 of 3 Material Safety Data Sheet DUET Dual- action Adulticide Date last revised: 6 June 2008 X. Additional Regulatory Information DOT (Department of Transportation) This material is not regulated by the DOT as a hazardous material when shipped in Non -Bulk quantities (i.e., less than 119 Gallons 1 450 Liters). When shipping in Bulk- quantities (i.e., more than 119 Gallons / 450 Liters), please contact Clarke Mosquito Control for the proper shipping description. AIR (ICAO/IATA) Shipping Name: Insecticides, Insect or Animal Repellent, Liquid, N.O.S. Primary Hazard Class/Division: Non - hazardous SARA Title III (Superfund Amendments and Reauthorization Act) 311/312 Hazard Categories: FIRE: NO I PRESSURE GENERATING: NO 1 REACTIVITY: NO ACUTE: YE 313 Reportable Ingredients (Component, CAS #, Max %) : Piperonyl butoxide, 000051 -03 -6, 5.0 d- Phenothrin (Sumithrin ®), 026002 -80 -2, 5.00 302/304 Emergency Planning Emergency Plan: There are no SARA Title III Section 302 extremely hazardous substances present in this formulation (40 CFR 355). There are no components that are subject to emergency requirements under CERCLA Section 103(a) (40 CFR 302.4) in this formulation. TSCA (Toxic Substance Control Act) TSCA Status: All chemical substances found in this product comply with the Toxic Substances Control Act's inventory reporting requirements. State Regulations Volatile Organic Compounds (VOC): This product contains less than 1% VOCs. FIRE NFPA Code Key 4 = Severe 3 = Serious 2 = Moderate HEALTH o REACTIVTY 1 = Slight 0 = Minimal The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. A co 01.0 1 i'( LaheIs&MSDS 1Order Contact Us Making Can munif as Around The Wvld MaeLivade,Safe And Cantctade. OFFERINGS WHO WE SERVE ABOUT US EMERGENCY SUSTAINABILITY CLARK CARES INTERNATIONAL Integrated Environmental Management N ATU p R 1 L PYRE C T H I N Mosquito Control V � a n� [ V is Integrated Pest Management Program A natural chili i'n o control, natural pyrethrin provides an effe Products solution in a variety of areas. In addition, natural pyrethrin has fast knoc effective against resistant strains and has established crop Adulticides Anvil AquaAnvil AT- A- GLANCE EC61 AquaHalt Exceptional choice for outdoor locations around livestock and • horses, animal feeding areas CONVEN Biomist Duet For use with ULV and thermal fog equipment sDownl Flit Can be applied by ground or air Mosqu itoMaster Mosquitomist Natural Pyrethrin Larvicides Equipment, Technology and Tools Aquatic Services Emergency Services Residential Services What Solution Is Right For You? Call or snail us anytime. A Clarke Control Consultant will contact yat within two business hairs, CALL (800) 323 -5727 EMAIL U S! 4icklogw" Makes NPDES Compli ance Si mplel Learn moretoday Dow nloa d our 2010 -2011 Sustainability Report II iiii \ ee 40000 ,,,,,. SITE LIN KS Home Offerings Who We Serve About Us International Emergency Su stai nabi l ity Clarke Cares News &Events Media Area Privacy Pol i cy Terms GO APANYIN FORMAT W Our Story leadership Careers Contact Clarke GU STONER SERMCE Wgs MATERIAL SAFETY DATA SHEET Emergency Phone: 800 - 214 -7753 PRODUCT: NATULARTM 2EC Effective Date: 17 July 2012 US EPA Registration No.: 8329 -82 Development Code: GF -1592 1. PRODUCT AND COMPANY IDENTIFICATION I CANCER INFORMATION: Spinosad did not cause cancer in laboratory animals. PRODUCT: NATULARTM 2EC REPRODUCTIVE EFFECTS: Spinosad effects on COMPANY IDENTIFICATION: reproduction, in laboratory animal studies, have been seen Clarke Mosquito Control Products, Inc. only at doses that produced significant toxicity to the parent 110 E. Irving Park Road, 4"' Floor animals. Roselle, IL 60172 U.S.A. 1 4. FIRST AID: 1- 800 - 323 -5727 EYE: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, alter 2. INFORMATION ON INGREDIENTS: I the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Spinosad: Factor A CAS# 131929 -60-7 Factor D CAS# 131929 -63-0 20.62% INGESTION: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of Other Ingredients*, proprietary 79.38% water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give This document is prepared pursuant to the OSHA Hazard anything by mouth to an unconscious person. Communication Standard (29 CFR 1910.1200). In addition, NOTE TO PHYSICIAN: Counsel patients about the clinical other substances not 'Hazardous per this OSHA Standard pa may be listed. Where proprietary ingredient shows, the manWestations of salicylate poisoning (e.g., tinnitus, acid - identity may be made available as provided in this standard. base disturbance, fluid and electrolyte imbalances, CNS effects). Supportive care. Treatment based on judgment of 3. HAZARDS IDENTIFICATION: J the physician in response to reactions of the patient. POTENTIAL HEALTH EFFECTS: This section includes (5. FIRE FIGHTING MEASURES: possible adverse effects, which could occur if this material is not handled in the recommended manner. FLASH POINT: 99° C (210.2 °F) METHOD USED: Closed cup (ASTM D93) EYE: May cause transient (temporary) eye irritation. Vapors from product may be irritating to mucous membranes, FLAMMABLE UMITS: including the eyes. LFL: Not established UFL: Not established SKIN: Short term exposure may cause temporary irritation. Can be absorbed through the skin. The LD50 for skin FIRE AND EXPLOSION HAZARDS: Material is not absorption in rats is >5000 mg/kg. A single prolonged pyrophoric. exposure is not likely to result in the material being absorbed in harmful amounts. Natular 2EC did not cause allergic skin EXTINGUISHING MEDIA: Regular dry chemical, carbon irritation or reactions when tested in guinea pigs. dioxide, water, regular foam. Large fires: Use regular foam or flood with fine water spray. INGESTION: Harmful if swallowed. The oral LD50 for rats is 5,000 mg/kg. Small amounts swallowed incidental to normal FIRE - FIGHTING PRECAUTIONS: Move container from fire handling operations are not likely to cause injury; however, area if it can be done without risk. Do not scatter spilled swallowing larger amounts may cause injury. If large material with high- pressure water streams. Dike for later quantities of this material are swallowed, call a physician disposal. Use extinguishing agents appropriate for immediately. Symptoms of poisoning include nausea, surrounding fire. Avoid inhalation of material or combustion vomiting, acidosis, pulmonary edema, pneumonia, and by- products. Stay upwind and keep out of low areas. convulsions. FIRE AND EXPLOSION HAZARDS: Keep people away. INHALATION: Short term exposure may result in respiratory Isolate fire area and deny unnecessary entry. Under fire tract irritation. The inhalation LC50 for the formulation is conditions some components may decompose. Combustion greater than 2.01 mg/L. Acute exposure to concentrate mist products may include CO and NOxtypical of wood smoke. is not likely to cause adverse effects. - I MATERIAL SAFETY DATA SHEET Emergency Phone: 800- 214 -7753 PRODUCT: NATULARTM 2EC Effective Date: 17 July 2012 US EPA Registration No.: 8329 -82 Development Code: GF -1592 6. ACCIDENTAL RELEASE MEASURES: ( SOLUBILITY IN WATER: slightly soluble pH: 7— 8 ACTION TO TAKE FOR SPILLS /LEAKS: Stop leak if VISCOSITY: 17.32 (20C), 8.59 (40C) possible without personal risk. Small spills: Absorb with sand or other non - combustible material. Collect spilled material in 110. STABILITY AND REACTIVITY: appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. STABILITY (CONDITIONS TO AVOID): Thermally stable at typical use and storage temperatures and pressure. Avoid 7. HANDLING AND STORAGE: heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. HANDLING: Keep out of reach of children. Avoid eye INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID): contact. Do not take internally. Wash thoroughly after handling and before eating, drinking, or smoking. Store Reactive with oxidizing agents, acids, alkalis. product in original container. See product label for additional instructions. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition products: forms carbon monoxide and /or STORAGE: Product should be stored in compliance with dioxide upon buming. local regulations. Store in a cool, dry, well- ventilated place in the original container. Protect from excessive heat and cold. HAZARDOUS POLYMERIZATION: Not known to occur. Do not store near food, drink, animal feed, pharmaceuticals, cosmetics or fertilizers. Keep out of mach of children. 111. TOXICOLOGICAL INFORMATION: I 18. EXPOSURE CONTROLS /PERSONAL PROTECTION: I MUTAGENICITY: For spinosad, in -vitro and animal mutagenicity studies were negative. These precautions are suggested for conditions where the TOXICITY DATA: > 5000 oral rat LD50 potential for exposure exists. Emergency conditions may k9 require additional precautions. — 2000 mg/kg dermal rat LD50 > 2.01 mg/L inhalation rat LC50 EXPOSURE GUIDELINES: Spinosad: Dow AgroSciences Industrial Hygiene Guide is 0.3 mg/M TWA. LOCAL EFFECTS: Mild irritant: inhalation, skin, eye ACUTE TOXICITY LEVEL: Slightly toxic, ingestion li OSHA PEL/STEL: Not established. CHRONIC TOXICITY: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated ingestion may ENGINEERING CONTROLS: Good general ventilation be toxic to kidneys, liver, heart, CNS. should be sufficient for most conditions. Additional information provided in Section 3. RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING 112. DISPOSAL CONSIDERATIONS: WORKERS: DISPOSAL METHOD: Improper disposal of excess product EYE/FACE PROTECTION: Use of protective eyewear is or rinsate is a violation of the Federal law. If these wastes recommended. cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control CLOTHING: No precautions other than clean body - covering Agency, or the Hazardous Waste Representative at the clothing and chemical resistant gloves should be needed. nearest EPA regional office for guidance. See product label for additional instructions. Follow product label instructions for container disposal. APPLICATORS AND ALL OTHER HANDLERS: Wear protective eyewear. 113. TRANSPORT INFORMATION: 19. PHYSICAL AND CHEMICAL PROPERTIES: 1 DOT Bulk and Non -Bulk: NOT REGULATED APPEARANCE: light tan to golden liquid, oily IMDG ODOR: characteristic of wintergreen (mint) Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS DENSITY: 1.16 g /ml SUBSTANCE SOLID, N.O.S. VAPOR PRESSURE: 1 mmHg © 20 C Technical Name: Spinosad VAPOR DENSITY (air =1): 5 Hazard Class: 9 ID Number. UN3077 Packing Group: III - 2 - MATERIAL SAFETY DATA SHEET Emergency Phone: 800-214-7753 PRODUCT: NATULARTM 2EC Effective Date: 17 July 2012 US EPA Registration No.: 8329 -82 Development Code: GF -1592 Marine Pollutant: Yes ICAO/IATA: NOT REGULATED Additional Information: MARINE POLLUTANT Spinosad 14. REGULATORY INFORMATION: NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ from one location to another, it is the buyer's responsibility to ensure that its activities comply with federal, state or provincial, and local laws. The following specific information is made for the purpose of complying with numerous federal, state or provincial, and local laws and regulations. U.S. REGULATIONS SARA 313 INFORMATION: This product contains no chemical subject to SARA Title III Section 313 supplier notification requirements. SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate (acute) hazard STATE RIGHT-TO-KNOW: The following product components are cited on certain state lists as mentioned. Non - listed components may be shown in the composition section of the MSDS. None COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND UABIUTY ACT (CERCLA, or SUPERFUND): This product contains no chemical subject to reporting under CERCLA. OSHA HAZARD COMMUNICATION STANDARD: This product is a "Hazardous Chemical° as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. The information herein is given in good faith, but no warranty, express or implied, is made. Consult Clarke Mosquito Control Products, Inc. for further Information. - 3 -